全文获取类型
收费全文 | 1030篇 |
免费 | 190篇 |
国内免费 | 121篇 |
专业分类
化学 | 135篇 |
力学 | 147篇 |
综合类 | 3篇 |
数学 | 491篇 |
物理学 | 565篇 |
出版年
2024年 | 3篇 |
2023年 | 4篇 |
2022年 | 18篇 |
2021年 | 15篇 |
2020年 | 21篇 |
2019年 | 29篇 |
2018年 | 43篇 |
2017年 | 34篇 |
2016年 | 43篇 |
2015年 | 47篇 |
2014年 | 83篇 |
2013年 | 93篇 |
2012年 | 54篇 |
2011年 | 52篇 |
2010年 | 50篇 |
2009年 | 72篇 |
2008年 | 68篇 |
2007年 | 68篇 |
2006年 | 62篇 |
2005年 | 73篇 |
2004年 | 54篇 |
2003年 | 48篇 |
2002年 | 45篇 |
2001年 | 36篇 |
2000年 | 36篇 |
1999年 | 30篇 |
1998年 | 31篇 |
1997年 | 22篇 |
1996年 | 22篇 |
1995年 | 15篇 |
1994年 | 10篇 |
1993年 | 10篇 |
1992年 | 8篇 |
1991年 | 8篇 |
1990年 | 5篇 |
1989年 | 5篇 |
1988年 | 4篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 4篇 |
1984年 | 3篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1976年 | 1篇 |
1957年 | 2篇 |
排序方式: 共有1341条查询结果,搜索用时 15 毫秒
41.
In spite of large spin coherence length in graphene due to small spin–orbit coupling, the created potential barrier and antiferromagnetic coupling at graphene/transition metal (TM) contacts strongly reduce the spin transport behavior in graphene. Keeping these critical issues in mind in the present work, ferromagnetic (Co, Ni) nanosheets are grown on graphene surface to elucidate the nature of interaction at the graphene/ferromagnetic interface to improve the spin transistor characteristics. Temperature dependent magnetoconductance shows unusual behavior exhibiting giant enhancement in magnetoconductance with increasing temperature. A model based on spin–orbit coupling operated at the graphene/TM interface is proposed to explain this anomalous result. We believe that the device performance can be improved remarkably tuning the spin–orbit coupling at the interface of graphene based spin transistor. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献
42.
We study a spin structure that arises in a one‐dimensional quantum dot with zero total spin under the action of a charged tip of a scanning probe microscope in the presence of a weak magnetic field. The evolution of spin structure with changing the probe position is traced to show that the movable probe can be an effective tool to manipulate the spin. The spin structures are formed when the probe is located in certain regions along the dot due to Coulomb interaction of electrons as they are redistributed between the two sections in which the quantum dot is divided by the potential barrier created by the probe. There are two main states: spin‐polarized and non‐polarized ones. The transition between them is accompanied by a spin precession governed by the Rashba spin–orbit interaction induced by the electric field of the probe. In the transition region the spin density changes strongly while charge distribution remains nearly unchanged. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献
43.
44.
We investigate the electron spin–orbit interaction anisotropy of pyramidal InAs quantum dots using a fully three-dimensional Hamiltonian. The dependence of the spin–orbit interaction strength on the orientation of externally applied in-plane magnetic fields is consistent with recent experiments, and it can be explained from the interplay between Rashba and Dresselhaus spin–orbit terms in dots with asymmetric confinement. Based on this, we propose manipulating the dot composition and height as efficient means for controlling the spin–orbit anisotropy. 相似文献
45.
Regiospecific Formation and Unusual Optical Properties of 2,5‐Bis(arylethynyl)rhodacyclopentadienes: A New Class of Luminescent Organometallics 下载免费PDF全文
Dr. Andreas Steffen Dr. Richard M. Ward Dr. Meng Guan Tay Dr. Robert M. Edkins Dr. Fabian Seeler Magda van Leeuwen Dr. Lars‐Olof Pålsson Prof. Dr. Andrew Beeby Dr. Andrei S. Batsanov Prof. Dr. Judith A. K. Howard Prof. Dr. Todd B. Marder 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(13):3652-3666
A series of 2,5‐bis(arylethynyl)rhodacyclopentadienes has been prepared by a rare example of regiospecific reductive coupling of 1,4‐(p‐R‐phenyl)‐1,3‐butadiynes (R?H, Me, OMe, SMe, NMe2, CF3, CO2Me, CN, NO2, ?C?C‐(p‐C6H4?NHex2), ?C?C?(p‐C6H4?CO2Oct)) at [RhX(PMe3)4] ( 1 ) (X=?C?C?SiMe3 ( a ), ?C?C‐(p‐C6H4?NMe2) ( b ), ?C?C?C?C?(p‐C6H4?NPh2) ( c ) or ?C?C?{p‐C6H4‐C?C?(p‐C6H4‐N(C6H13)2)} ( d ) or Me ( e )), giving the 2,5‐bis(arylethynyl) isomer exclusively. The rhodacyclopentadienes bearing a methyl ligand in the equatorial plane (compound 1 e ) have been converted into their chloro analogues by reaction with HCl etherate. The rhodacycles thus obtained are stable to air and moisture in the solid state and the acceptor‐substituted compounds are even stable to air and moisture in solution. The photophysical properties of the rhodacyclopentadienes are highly unusual in that they exhibit, exclusively, fluorescence between 500–800 nm from the S1 state, with quantum yields of Φ=0.01–0.18 and short lifetimes (τ=0.45–8.20 ns). The triplet state formation (ΦISC=0.57 for 2 a ) is exceptionally slow, occurring on the nanosecond timescale. This is unexpected, because the Rh atom should normally facilitate intersystem crossing within femto‐ to picoseconds, leading to phosphorescence from the T1 state. This work therefore highlights that in some transition‐metal complexes, the heavy atom can play a more subtle role in controlling the photophysical behavior than is commonly appreciated. 相似文献
46.
Liangliang Liang Wei Yan Xian Qin Xiao Peng Han Feng Yu Wang Ziyu Zhu Lingmei Liu Yu Han Qinghua Xu Junle Qu Xiaogang Liu 《Angewandte Chemie (International ed. in English)》2020,59(2):746-751
Stimulated emission depletion (STED) microscopy enables ultrastructural imaging of biological samples with high spatiotemporal resolution. STED nanoprobes based on fluorescent organosilica nanohybrids featuring sub‐2 nm size and near‐unity quantum yield are presented. The spin–orbit coupling (SOC) of heavy‐atom‐rich organic fluorophores is mitigated through a silane‐molecule‐mediated condensation/dehalogenation process, resulting in bright fluorescent organosilica nanohybrids with multiple emitters in one hybrid nanodot. When harnessed as STED nanoprobes, these fluorescent nanohybrids show intense photoluminescence, high biocompatibility, and long‐term photostability. Taking advantage of the low‐power excitation (0.5 μW), prolonged singlet‐state lifetime, and negligible depletion‐induced re‐excitation, these STED nanohybrids present high depletion efficiency (>96 %), extremely low saturation intensity (0.54 mW, ca. 0.188 MW cm?2), and ultra‐high lateral resolution (ca. λem/28). 相似文献
47.
The application of quantum dots in advanced technology goes beyond doubt. Here, based on an analytical methodology, investigate a three-electron-quantum dot in the presence of Rashba spin–orbit interaction under cylindrical symmetry. Both eigenvalues and eigenfunctions of the system are reported and the problem is numerically discussed. 相似文献
48.
Investigations of low energy transfer trajectories are important for both celestial mechanics and astronautics. Methodologies using the theories from dynamical systems are developed in recent years. This paper investigates the dynamics of the earth-moon system. Low energy transfer trajectories are solved numerically by employing a hybrid strategy: first, a genetic hide and seek method performs a search in large domain to confine the global minimum f(η) (objective function) region; then, a deterministic Nelder-Mead method is utilized to refine the minimum quickly. Some transfer trajectories of the spacecraft in the earth-moon system are successfully simulated which verify the desired efficiency and robustness of the method of this paper. 相似文献
49.
61. IntroductionLet P be a submanifold of an n-dimensional riemannian manifold AI. Expressions fOrthe kth integrated mean curvatures, M^P(t), (i. e. the integral of tho kth mcan curvature,k = 0, 1,' l n -- l), of a tubular hypersurface P of radius t about P, in terms of theRiemann curvature tensor of P. are calculated when AI is Euclidean or a rank one symmetricspace[5'13"1. Moreover, when P is a closed convex hypersurface of thc n-dimensional spaceof constant curvature A', Santal6 has… 相似文献
50.
§ 1 IntroductionIn this note we are concerned with the asymptotically periodic second order equation-u″+α( x) u =β( x) uq +γ( x) up, x∈ R,( 1 )where1
相似文献